A novel poly(propylene-co-imidazole) based biofuel cell: System optimization and operation for energy generation

This study describes the construction of an enzymatic fuel cell comprised of novel gold nanoparticles embedded poly(propylene-co-imidazole) coated anode and cathode. Working electrode fabrication steps and operational conditions for the fuel cell have been optimized to get enhanced power output. Electrical generation capacity of the optimized cell was tested by using the municipal wastewater sample. The enzymatic fuel cell system reached to maximum power density with 1 µg and 8 µg of polymer quantity and bilirubin oxidase on electrode surface, respectively. The maximum power output was calculated to be 5 µW cm- 2 at + 0.56 V (vs. Ag/AgCl) in phosphate buffer (pH 7.4, 100 mM, 20 °C) by the addition of 15 mM of glucose as a fuel source. The optimized enzymatic fuel cell generated a power density of 0.46 µW cm- 2 for the municipal wastewater sample. Poly(propylene-co-imidazole) was easily used for a fuel cell system owing to its metallic nanoparticle content. The developed fuel cell will play a significant role for energy conversion by using glucose readily found in wastewater and in vivo mediums. © 2014 Elsevier B.V. All rights reserved.

Eser Adı
[dc.title]
A novel poly(propylene-co-imidazole) based biofuel cell: System optimization and operation for energy generation
Yazar
[dc.contributor.author]
Kılıç, Muhammet Samet
Yazar
[dc.contributor.author]
Korkut, Şeyda
Yazar
[dc.contributor.author]
Hazer, Baki
Yayın Yılı
[dc.date.issued]
2015
Yayıncı
[dc.publisher]
Elsevier Ltd
Yayın Türü
[dc.type]
article
Özet
[dc.description.abstract]
This study describes the construction of an enzymatic fuel cell comprised of novel gold nanoparticles embedded poly(propylene-co-imidazole) coated anode and cathode. Working electrode fabrication steps and operational conditions for the fuel cell have been optimized to get enhanced power output. Electrical generation capacity of the optimized cell was tested by using the municipal wastewater sample. The enzymatic fuel cell system reached to maximum power density with 1 µg and 8 µg of polymer quantity and bilirubin oxidase on electrode surface, respectively. The maximum power output was calculated to be 5 µW cm- 2 at + 0.56 V (vs. Ag/AgCl) in phosphate buffer (pH 7.4, 100 mM, 20 °C) by the addition of 15 mM of glucose as a fuel source. The optimized enzymatic fuel cell generated a power density of 0.46 µW cm- 2 for the municipal wastewater sample. Poly(propylene-co-imidazole) was easily used for a fuel cell system owing to its metallic nanoparticle content. The developed fuel cell will play a significant role for energy conversion by using glucose readily found in wastewater and in vivo mediums. © 2014 Elsevier B.V. All rights reserved.
Kayıt Giriş Tarihi
[dc.date.accessioned]
2019-12-23
Açık Erişim Tarihi
[dc.date.available]
2019-12-23
Yayın Dili
[dc.language.iso]
eng
Konu Başlıkları
[dc.subject]
Bilirubin oxidase
Konu Başlıkları
[dc.subject]
Glucose oxidase
Konu Başlıkları
[dc.subject]
Gold nanoparticles
Konu Başlıkları
[dc.subject]
Poly(propylene-co-imidazole)
Künye
[dc.identifier.citation]
Kilic, M. S., Korkut, S. ve Hazer, B. (2015). A novel poly(Propylene-co-imidazole) based biofuel cell: System optimization and operation for energy generation. Materials Science and Engineering: C, 47, 165-171. doi:10.1016/j.msec.2014.10.077
Haklar
[dc.rights]
info:eu-repo/semantics/closedAccess
ISSN
[dc.identifier.issn]
0928-4931
Sponsor YAYINCI
[dc.description.sponsorship]
112Y100, 211T016
Sponsor YAYINCI
[dc.description.sponsorship]
This work was financially supported by; both “ The Scientific & Technological Research Council of Turkey ” (TUBITAK) (Grant nos. 112Y100 and 211T016 ) and the Bulent Ecevit University Research Fund (Grant nos. BEU-2012-10-03-13 and BEU-2013-77047330-01 ).
İlk Sayfa Sayısı
[dc.identifier.startpage]
165
Son Sayfa Sayısı
[dc.identifier.endpage]
171
Dergi Adı
[dc.relation.journal]
Materials Science and Engineering C
Dergi Cilt Bilgisi
[dc.identifier.volume]
47
Tek Biçim Adres
[dc.identifier.uri]
https://dx.doi.org/10.1016/j.msec.2014.10.077
Tek Biçim Adres
[dc.identifier.uri]
https://hdl.handle.net/20.500.12628/4004
Görüntülenme Sayısı ( Şehir )
Görüntülenme Sayısı ( Ülke )
Görüntülenme Sayısı ( Zaman Dağılımı )
Görüntülenme
67
09.12.2022 tarihinden bu yana
İndirme
1
09.12.2022 tarihinden bu yana
Son Erişim Tarihi
25 Şubat 2024 07:50
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Tıklayınız
enzymatic optimized wastewater glucose density system electrode maximum municipal sample output generated source buffer addition Poly(propylene-co-imidazole) readily reserved rights Elsevier mediums conversion easily energy significant developed content nanoparticle metallic phosphate surface Ag/AgCl) conditions operational fabrication
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