One-Pot Synthesis of Poly(linoleic acid)-g-Poly(styrene)-g-Poly(epsilon-caprolactone) Graft Copolymers

One-pot synthesis of graft copolymers by ring-opening polymerization and free radical polymerization using polymeric linoleic acid peroxide (PLina) is reported. Graft copolymers having structures of poly(linoleic acid)-g-polystyrene-g-poly(epsilon-caprolactone) were synthesized from PLina, possessing peroxide groups on the main chain by the combination of free radical polymerization of styrene and ring-opening polymerization of epsilon-caprolactone in one-step. Principal parameters, such as monomer concentration, initiator concentration, and polymerization time, which effect the one-pot polymerization reactions were evaluated. The obtained graft copolymers were characterized by H-1-NMR and DOSY-NMR spectroscopy, gel permeation chromatography, thermal gravimetric analysis and differential scanning calorimetry techniques.

Dergi Adı JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY
Dergi Cilt Bilgisi 91
Dergi Sayısı 5
Sayfalar 849 - 858
Yayın Yılı 2014
Eser Adı
[dc.title]
One-Pot Synthesis of Poly(linoleic acid)-g-Poly(styrene)-g-Poly(epsilon-caprolactone) Graft Copolymers
Yazar
[dc.contributor.author]
Allı, Abdulkadir
Yazar
[dc.contributor.author]
Allı, Sema
Yazar
[dc.contributor.author]
Becer, C. Remzi
Yazar
[dc.contributor.author]
Hazer, Baki
Yayın Yılı
[dc.date.issued]
2014
Yayıncı
[dc.publisher]
SPRINGER
Yayın Türü
[dc.type]
article
Özet
[dc.description.abstract]
One-pot synthesis of graft copolymers by ring-opening polymerization and free radical polymerization using polymeric linoleic acid peroxide (PLina) is reported. Graft copolymers having structures of poly(linoleic acid)-g-polystyrene-g-poly(epsilon-caprolactone) were synthesized from PLina, possessing peroxide groups on the main chain by the combination of free radical polymerization of styrene and ring-opening polymerization of epsilon-caprolactone in one-step. Principal parameters, such as monomer concentration, initiator concentration, and polymerization time, which effect the one-pot polymerization reactions were evaluated. The obtained graft copolymers were characterized by H-1-NMR and DOSY-NMR spectroscopy, gel permeation chromatography, thermal gravimetric analysis and differential scanning calorimetry techniques.
Açıklama
[dc.description]
WOS: 000335153500016
Kayıt Giriş Tarihi
[dc.date.accessioned]
2019-12-23
Açık Erişim Tarihi
[dc.date.available]
2019-12-23
Yayın Dili
[dc.language.iso]
eng
Konu Başlıkları
[dc.subject]
Autoxidation
Konu Başlıkları
[dc.subject]
One-pot polymerization
Konu Başlıkları
[dc.subject]
epsilon-Caprolactone
Konu Başlıkları
[dc.subject]
Polymeric linoleic acid peroxides
Künye
[dc.identifier.citation]
Allı, A., Allı, S., Becer, C. R. ve Hazer, B.. (2014). One-Pot Synthesis of Poly(linoleic acid)-g-Poly(styrene)-g-Poly(ε-caprolactone) Graft Copolymers. Journal of the American Oil Chemists Society. Journal of the American Oil Chemists Society. doi:10.1007/s11746-014-2418-1
Haklar
[dc.rights]
info:eu-repo/semantics/closedAccess
ISSN
[dc.identifier.issn]
0003-021X
ISSN
[dc.identifier.issn]
1558-9331
Sponsor YAYINCI
[dc.description.sponsorship]
Turkish Scientific Research CouncilTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [110T884, 211T016]; Duzce University Research FundDuzce University [2011.05.HD.026, 2011.05.03.068, 2011.05.HD.052]; Bulent Ecevit University Research FundBulent Ecevit University [2012-10-03-03]
Sponsor YAYINCI
[dc.description.sponsorship]
This work was supported financially by the Turkish Scientific Research Council (Grants Numbers: 110T884, 211T016), the Duzce University Research Fund (Grant Number: 2011.05.HD.026, 2011.05.03.068, 2011.05.HD.052) the Bulent Ecevit University Research Fund (Grant Number: 2012-10-03-03).
İlk Sayfa Sayısı
[dc.identifier.startpage]
849
Son Sayfa Sayısı
[dc.identifier.endpage]
858
Dergi Adı
[dc.relation.journal]
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY
Dergi Sayısı
[dc.identifier.issue]
5
Dergi Cilt Bilgisi
[dc.identifier.volume]
91
Tek Biçim Adres
[dc.identifier.uri]
https://dx.doi.org/10.1007/s11746-014-2418-1
Tek Biçim Adres
[dc.identifier.uri]
https://hdl.handle.net/20.500.12628/3035
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33
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1
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polymerization copolymers ring-opening radical concentration peroxide obtained evaluated reactions One-pot one-pot effect characterized monomer initiator chromatography H-1-NMR DOSY-NMR spectroscopy permeation thermal gravimetric analysis differential scanning calorimetry techniques combination parameters acid)-g-polystyrene-g-poly(epsilon-caprolactone) polymeric linoleic (PLina) reported having
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