Synthesis of block/graft copolymers based on vinyl benzyl chloride via reversible addition fragmentation chain transfer (RAFT) polymerization using the carboxylic acid functionalized Trithiocarbonate

Reversible Addition-Fragmentation Chain-Transfer (RAFT) polymerization of styrene (St), vinyl benzyl chloride (vbc), tert-butyl methacrylate (tertBMA) and n-butyl methacrylate (nBMA) was investigated using carboxylic acid functionalized trithiocarbonate (R2). A series of random copolymer of styrene and vinyl benzyl chloride was prepared in order to control chloromethyl functionality in the copolymer, via RAFT polymerization. Addition to this, first-order kinetic behavior of the RAFT polymerization of vbc using R2 was also evaluated. A novel series of amphiphilic copolymers based on polyethylene glycol (PEG) with molar masses of 500 and 2000 g/mol, functionalized polyvinyl benzyl chloride (Pvbc) were obtained via the Williamson-ether-synthesis. As chloromethyl functionality increases, the introduced PEG increases. Fractional precipitation, thermal properties and water uptakes of the amphiphilic polymer samples were evaluated. The new polymers can be the promising materials with high aqueous solubility capacity. © 2019, The Polymer Society, Taipei.

Eser Adı
[dc.title]
Synthesis of block/graft copolymers based on vinyl benzyl chloride via reversible addition fragmentation chain transfer (RAFT) polymerization using the carboxylic acid functionalized Trithiocarbonate
Yazar
[dc.contributor.author]
Hazer, Baki
Yazar
[dc.contributor.author]
Arslan, Hülya
Yazar
[dc.contributor.author]
Senemoğlu, Yetkin
Yazar
[dc.contributor.author]
Şen, Şadi
Yayın Yılı
[dc.date.issued]
2019
Yayıncı
[dc.publisher]
Springer Netherlands
Yayın Türü
[dc.type]
article
Özet
[dc.description.abstract]
Reversible Addition-Fragmentation Chain-Transfer (RAFT) polymerization of styrene (St), vinyl benzyl chloride (vbc), tert-butyl methacrylate (tertBMA) and n-butyl methacrylate (nBMA) was investigated using carboxylic acid functionalized trithiocarbonate (R2). A series of random copolymer of styrene and vinyl benzyl chloride was prepared in order to control chloromethyl functionality in the copolymer, via RAFT polymerization. Addition to this, first-order kinetic behavior of the RAFT polymerization of vbc using R2 was also evaluated. A novel series of amphiphilic copolymers based on polyethylene glycol (PEG) with molar masses of 500 and 2000 g/mol, functionalized polyvinyl benzyl chloride (Pvbc) were obtained via the Williamson-ether-synthesis. As chloromethyl functionality increases, the introduced PEG increases. Fractional precipitation, thermal properties and water uptakes of the amphiphilic polymer samples were evaluated. The new polymers can be the promising materials with high aqueous solubility capacity. © 2019, The Polymer Society, Taipei.
Kayıt Giriş Tarihi
[dc.date.accessioned]
2019-12-23
Açık Erişim Tarihi
[dc.date.available]
2019-12-23
Yayın Dili
[dc.language.iso]
eng
Konu Başlıkları
[dc.subject]
Block copolymer
Konu Başlıkları
[dc.subject]
Comb type graft copolymer
Konu Başlıkları
[dc.subject]
nButyl methacrylate
Konu Başlıkları
[dc.subject]
Polyethylene glycol
Konu Başlıkları
[dc.subject]
RAFT polymerization
Konu Başlıkları
[dc.subject]
TertButyl methacrylate
Konu Başlıkları
[dc.subject]
Vinyl benzyl chloride
Künye
[dc.identifier.citation]
Hazer, B., Arslan, H., Senemoğlu, Y. ve Şen, Ş. (2019). Synthesis of block/graft copolymers based on vinyl benzyl chloride via reversible addition fragmentation chain transfer (Raft) polymerization using the carboxylic acid functionalized Trithiocarbonate. Journal of Polymer Research, 26(5), 101. doi:10.1007/s10965-019-
Haklar
[dc.rights]
info:eu-repo/semantics/closedAccess
ISSN
[dc.identifier.issn]
1022-9760
Sponsor YAYINCI
[dc.description.sponsorship]
Bülent Ecevit Üniversitesi: BAGP-001, -2017-72118496-01
Sponsor YAYINCI
[dc.description.sponsorship]
Acknowledgments This work was supported by the Bülent Ecevit University Research Funds (#BEU-2017-72118496-01) and Kapadokya University KÜN.2018-BAGP-001. This paper has been proofread by Bülent Ecevit University Article Proofreading and Editing Office.
Dergi Adı
[dc.relation.journal]
Journal of Polymer Research
Dergi Sayısı
[dc.identifier.issue]
5
Dergi Cilt Bilgisi
[dc.identifier.volume]
26
Tek Biçim Adres
[dc.identifier.uri]
https://dx.doi.org/10.1007/s10965-019-1763-z
Tek Biçim Adres
[dc.identifier.uri]
https://hdl.handle.net/20.500.12628/7765
Görüntülenme Sayısı ( Şehir )
Görüntülenme Sayısı ( Ülke )
Görüntülenme Sayısı ( Zaman Dağılımı )
Görüntülenme
20
09.12.2022 tarihinden bu yana
İndirme
1
09.12.2022 tarihinden bu yana
Son Erişim Tarihi
10 Şubat 2024 21:30
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Tıklayınız
polymerization benzyl chloride copolymer evaluated functionalized series chloromethyl functionality increases styrene methacrylate amphiphilic obtained (Pvbc) uptakes properties thermal Williamson-ether-synthesis precipitation Fractional introduced Reversible polymer aqueous Taipei Society Polymer capacity solubility samples materials promising polymers 2000 g/mol
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