Synthesis and characterization of novel rod-coil (tadpole) poly(linoleic acid) based graft copolymers

Synthesis of novel poly (styrene)-g-poly(linoleic acid)-g-poly(ethylene glycol) amphiphilic rod-coil tadpole and poly (styrene)-g-poly(linoleic acid)-g-poly (dimethyl siloxane) double hydrophobic rod-coil tadpole graft copolymers have been reported. In the first step, poly(linoleic acid) peroxide macro initiator (PLina) was prepared by exposing linoleic acid to air at room temperature for three weeks, in view of the autoxidation process. In the second step, poly styrene-g-poly linoleic acid graft copolymer (PLinaS) was prepared by the polymerization of styrene initiated by PLina. In the third step, PS-g-PLina-g-PEG rod-coil tadpole amphiphilic graft copolymer and PS-g-PLina-g-PolyPDMS rod-coil tadpole double hydrophobic graft copolymers were obtained by the reaction of carboxylic ends of PLinaS with polyethylene glycol (PEG) with primary amine terminal and poly (dimethyl siloxane) (PDMS) with primary amine terminals. The target copolymers and all intermediates were well characterized by GPC, FTIR, 1H NMR, DSC, and TGA in detail. © 2015, Springer Science+Business Media Dordrecht.

Dergi Adı Journal of Polymer Research
Dergi Cilt Bilgisi 23
Dergi Sayısı 1
Sayfalar 1 - 10
Yayın Yılı 2016
Eser Adı
[dc.title]
Synthesis and characterization of novel rod-coil (tadpole) poly(linoleic acid) based graft copolymers
Yazar
[dc.contributor.author]
İnce, Özge
Yazar
[dc.contributor.author]
Akyol, Elvan
Yazar
[dc.contributor.author]
Sulu, Elvan
Yazar
[dc.contributor.author]
Şanal, Timur
Yazar
[dc.contributor.author]
Hazer, Baki
Yayın Yılı
[dc.date.issued]
2016
Yayıncı
[dc.publisher]
Springer Netherlands
Yayın Türü
[dc.type]
article
Özet
[dc.description.abstract]
Synthesis of novel poly (styrene)-g-poly(linoleic acid)-g-poly(ethylene glycol) amphiphilic rod-coil tadpole and poly (styrene)-g-poly(linoleic acid)-g-poly (dimethyl siloxane) double hydrophobic rod-coil tadpole graft copolymers have been reported. In the first step, poly(linoleic acid) peroxide macro initiator (PLina) was prepared by exposing linoleic acid to air at room temperature for three weeks, in view of the autoxidation process. In the second step, poly styrene-g-poly linoleic acid graft copolymer (PLinaS) was prepared by the polymerization of styrene initiated by PLina. In the third step, PS-g-PLina-g-PEG rod-coil tadpole amphiphilic graft copolymer and PS-g-PLina-g-PolyPDMS rod-coil tadpole double hydrophobic graft copolymers were obtained by the reaction of carboxylic ends of PLinaS with polyethylene glycol (PEG) with primary amine terminal and poly (dimethyl siloxane) (PDMS) with primary amine terminals. The target copolymers and all intermediates were well characterized by GPC, FTIR, 1H NMR, DSC, and TGA in detail. © 2015, Springer Science+Business Media Dordrecht.
Kayıt Giriş Tarihi
[dc.date.accessioned]
2019-12-23
Açık Erişim Tarihi
[dc.date.available]
2019-12-23
Yayın Dili
[dc.language.iso]
eng
Konu Başlıkları
[dc.subject]
Amphiphilic graft copolymer
Konu Başlıkları
[dc.subject]
Autoxidation
Konu Başlıkları
[dc.subject]
Poly (linoleic acid)
Konu Başlıkları
[dc.subject]
Poly(ethylene glycol) with amine terminals
Konu Başlıkları
[dc.subject]
Rod-coil tadpole
Künye
[dc.identifier.citation]
İnce, Ö., Akyol, E., Sulu, E., Şanal, T. ve Hazer, B. (2015). Synthesis and characterization of novel rod-coil (Tadpole) poly(Linoleic acid) based graft copolymers. Journal of Polymer Research, 23(1), 5. doi:10.1007/s10965-015-0894-0
Haklar
[dc.rights]
info:eu-repo/semantics/closedAccess
ISSN
[dc.identifier.issn]
1022-9760
İlk Sayfa Sayısı
[dc.identifier.startpage]
1
Son Sayfa Sayısı
[dc.identifier.endpage]
10
Dergi Adı
[dc.relation.journal]
Journal of Polymer Research
Dergi Sayısı
[dc.identifier.issue]
1
Dergi Cilt Bilgisi
[dc.identifier.volume]
23
Tek Biçim Adres
[dc.identifier.uri]
https://dx.doi.org/10.1007/s10965-015-0894-0
Tek Biçim Adres
[dc.identifier.uri]
https://hdl.handle.net/20.500.12628/7736
Görüntülenme Sayısı ( Şehir )
Görüntülenme Sayısı ( Ülke )
Görüntülenme Sayısı ( Zaman Dağılımı )
Görüntülenme
19
09.12.2022 tarihinden bu yana
İndirme
1
09.12.2022 tarihinden bu yana
Son Erişim Tarihi
07 Şubat 2024 11:36
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Tıklayınız
tadpole rod-coil copolymers prepared primary hydrophobic copolymer double siloxane) (dimethyl amphiphilic linoleic (styrene)-g-poly(linoleic terminal (PDMS) Synthesis polyethylene glycol PLinaS carboxylic reaction terminals target detail Dordrecht Science+Business Springer characterized intermediates obtained autoxidation PS-g-PLina-g-PolyPDMS (PLina) initiator peroxide
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