Newly designed bioanode for glucose/O2 biofuel cells to generate renewable energy

A copolymer poly(methyl methacrylate-co-vinylferrocene) was synthesized and used for the first time in a biofuel cell design. Bioanaode enzyme glucose oxidase and biocathode enzyme bilirubin oxidase were physically immobilized onto the copolymer-modified electrodes. Characterization studies were conducted by scanning electron microscopy, carbon-13, fourier transform infrared and hydrogen-1 nuclear magnetic resonance, and cyclic voltammograms. The designed biofuel cell was operated with linear sweep voltammetry. The maximum current was at 45°C with 120 µg of polymer amount. An improved power density of 323 µW cm-2 that is higher than other ferrocene-based fuel cells was obtained with 10-mM glucose at 0.4 V with the designed bioanode. © 2019 John Wiley & Sons Ltd.

Eser Adı
[dc.title]
Newly designed bioanode for glucose/O2 biofuel cells to generate renewable energy
Yazar
[dc.contributor.author]
Korkut, Şeyda
Yazar
[dc.contributor.author]
Kılıç, Muhammet Samet
Yazar
[dc.contributor.author]
Hazer, Baki
Yayın Yılı
[dc.date.issued]
2019
Yayıncı
[dc.publisher]
John Wiley and Sons Ltd
Yayın Türü
[dc.type]
article
Özet
[dc.description.abstract]
A copolymer poly(methyl methacrylate-co-vinylferrocene) was synthesized and used for the first time in a biofuel cell design. Bioanaode enzyme glucose oxidase and biocathode enzyme bilirubin oxidase were physically immobilized onto the copolymer-modified electrodes. Characterization studies were conducted by scanning electron microscopy, carbon-13, fourier transform infrared and hydrogen-1 nuclear magnetic resonance, and cyclic voltammograms. The designed biofuel cell was operated with linear sweep voltammetry. The maximum current was at 45°C with 120 µg of polymer amount. An improved power density of 323 µW cm-2 that is higher than other ferrocene-based fuel cells was obtained with 10-mM glucose at 0.4 V with the designed bioanode. © 2019 John Wiley & Sons Ltd.
Kayıt Giriş Tarihi
[dc.date.accessioned]
2019-12-23
Açık Erişim Tarihi
[dc.date.available]
2019-12-23
Yayın Dili
[dc.language.iso]
eng
Konu Başlıkları
[dc.subject]
biofuels
Konu Başlıkları
[dc.subject]
electrochemistry
Konu Başlıkları
[dc.subject]
fuel cell
Konu Başlıkları
[dc.subject]
renewable energy
Künye
[dc.identifier.citation]
Korkut, S., Kiliç, M. S. ve Hazer, B. (2019). Newly designed bioanode for glucose/O2 biofuel cells to generate renewable energy. Asia-Pacific Journal of Chemical Engineering, 14(6), e2374. doi:10.1002/apj.2374
Haklar
[dc.rights]
info:eu-repo/semantics/closedAccess
ISSN
[dc.identifier.issn]
1932-2135
Sponsor YAYINCI
[dc.description.sponsorship]
BEU-2013-77047330-01 112Y100
Sponsor YAYINCI
[dc.description.sponsorship]
This work was supported by the Scientific & Technological Research Council of Turkey (TUBITAK) under Grant 112Y100 and the Bulent Ecevit University Research Fund under Grant BEU-2013-77047330-01.
Dergi Adı
[dc.relation.journal]
Asia-Pacific Journal of Chemical Engineering
Dergi Sayısı
[dc.identifier.issue]
6
Dergi Cilt Bilgisi
[dc.identifier.volume]
14
Tek Biçim Adres
[dc.identifier.uri]
https://dx.doi.org/10.1002/apj.2374
Tek Biçim Adres
[dc.identifier.uri]
https://hdl.handle.net/20.500.12628/6753
Tam Metin İndirmek için tıklayın Ön izleme
Görüntülenme Sayısı ( Şehir )
Görüntülenme Sayısı ( Ülke )
Görüntülenme Sayısı ( Zaman Dağılımı )
Görüntülenme
38
09.12.2022 tarihinden bu yana
İndirme
1
09.12.2022 tarihinden bu yana
Son Erişim Tarihi
09 Şubat 2024 04:29
Google Kontrol
Tıklayınız
oxidase biofuel glucose designed enzyme density 323 µW improved amount polymer 120 µg current maximum voltammetry bioanode higher obtained ferrocene-based resonance linear immobilized physically bilirubin biocathode Bioanaode design copolymer-modified synthesized methacrylate-co-vinylferrocene) poly(methyl electrodes operated transform voltammograms cyclic
6698 sayılı Kişisel Verilerin Korunması Kanunu kapsamında yükümlülüklerimiz ve çerez politikamız hakkında bilgi sahibi olmak için alttaki bağlantıyı kullanabilirsiniz.

creativecommons
Bu site altında yer alan tüm kaynaklar Creative Commons Alıntı-GayriTicari-Türetilemez 4.0 Uluslararası Lisansı ile lisanslanmıştır.
Platforms