Reactions of anionic living polymers with bromomethyl-functionalized benzoyl peroxides
In order to synthesize benzoyl peroxide functionalized polystyrene (PSt), polyisoprene (PI) and poly(methyl methacrylate) (PMMA), anionic living PSt, PI, and PMMA were allowed to react with an excess amount of 4-(bromomethyl)benzoyl tert-butyl peroxide (BMtB) or bis[3,5-bis(bromomethyl)benzoyl] peroxide (BDBP) in tetrahydrofuran (THF) at -78°C. The results indicate that coupling reactions leading to dimers are significant during the reaction. Dimer formation was avoided when the living polystyrene was modified to the alcoholate anion by reaction with ethylene oxide (EO). © Wiley-VCH Verlag GmbH, 1999.
| Yazar |
Hazer, Baki Hirao, Akira Volga, Cüneyt |
| Yayın Türü | Article |
| Tek Biçim Adres | https://hdl.handle.net/20.500.12628/7316 |
| Tek Biçim Adres | 10.1002/(SICI)1521-3935(19990101)200:1<71::AID-MACP71>3.0.CO;2-D |
| Koleksiyonlar |
Fakülteler Fen Edebiyat Fakültesi Kimya Bölümü Makale Koleksiyonu (Kimya Bölümü) Araştırma Çıktıları | WoS | Scopus | TR-Dizin | PubMed | SOBİAD Scopus İndeksli Yayınlar Koleksiyonu Araştırma Çıktıları | WoS | Scopus | TR-Dizin | PubMed | SOBİAD WoS İndeksli Yayınlar Koleksiyonu |
| Dergi Adı | Macromolecular Chemistry and Physics |
| Dergi Cilt Bilgisi | 200 |
| Dergi Sayısı | 1 |
| Sayfalar | 71 - 76 |
| Yayın Yılı | 1999 |
| Eser Adı [dc.title] | Reactions of anionic living polymers with bromomethyl-functionalized benzoyl peroxides |
| Yazar [dc.contributor.author] | Hazer, Baki |
| Yazar [dc.contributor.author] | Hirao, Akira |
| Yazar [dc.contributor.author] | Volga, Cüneyt |
| Yayın Yılı [dc.date.issued] | 1999 |
| Yayıncı [dc.publisher] | Wiley-VCH Verlag |
| Yayın Türü [dc.type] | article |
| Özet [dc.description.abstract] | In order to synthesize benzoyl peroxide functionalized polystyrene (PSt), polyisoprene (PI) and poly(methyl methacrylate) (PMMA), anionic living PSt, PI, and PMMA were allowed to react with an excess amount of 4-(bromomethyl)benzoyl tert-butyl peroxide (BMtB) or bis[3,5-bis(bromomethyl)benzoyl] peroxide (BDBP) in tetrahydrofuran (THF) at -78°C. The results indicate that coupling reactions leading to dimers are significant during the reaction. Dimer formation was avoided when the living polystyrene was modified to the alcoholate anion by reaction with ethylene oxide (EO). © Wiley-VCH Verlag GmbH, 1999. |
| Kayıt Giriş Tarihi [dc.date.accessioned] | 2019-12-23 |
| Açık Erişim Tarihi [dc.date.available] | 2019-12-23 |
| Yayın Dili [dc.language.iso] | eng |
| Künye [dc.identifier.citation] | Hazer, B., Hirao, A. ve Volga, C. (1999). Reactions of anionic living polymers with bromomethyl-functionalized benzoyl peroxides. Macromolecular Chemistry and Physics, 200(1), 71-76. doi:10.1002/(SICI)1521-3935(19990101)200:1<71::AID-MACP71>3.0.CO;2-D |
| Haklar [dc.rights] | info:eu-repo/semantics/closedAccess |
| ISSN [dc.identifier.issn] | 1022-1352 |
| İlk Sayfa Sayısı [dc.identifier.startpage] | 71 |
| Son Sayfa Sayısı [dc.identifier.endpage] | 76 |
| Dergi Adı [dc.relation.journal] | Macromolecular Chemistry and Physics |
| Dergi Sayısı [dc.identifier.issue] | 1 |
| Dergi Cilt Bilgisi [dc.identifier.volume] | 200 |
| Tek Biçim Adres [dc.identifier.uri] | https://doi.org/10.1002/(SICI)1521-3935(19990101)200:1<71::AID-MACP71>3.0.CO;2-D |
| Tek Biçim Adres [dc.identifier.uri] | https://hdl.handle.net/20.500.12628/7316 |
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peroxide
reaction
polystyrene
living
significant
during
dimers
reactions
coupling
indicate
results
leading
modified
formation
avoided
-78°C
alcoholate
ethylene
Wiley-VCH
Verlag
synthesize
benzoyl
functionalized
polyisoprene
poly(methyl
methacrylate)
(PMMA)
anionic
allowed
excess
amount
4-(bromomethyl)benzoyl
tert-butyl
(BMtB)
5-bis(bromomethyl)benzoyl]
