(1RS,4RS)-1-Methoxyspiro[bicyclo[2.2.2]oct-5-ene-2,2'-[1', 3']dithiolane]

The preparation of (1RS,4RS)1-Methoxyspiro[bicyclo[2.2.2]oct-5-ene-2, 2'-[1',3 ']dithiolane] compound by a literature method was shown. The compound consists of a five-membered dithiolane ring with a methoxybicyclooctene spiro-fused at the 2-position. It was observed that the S atom of the dithiolane ring have electron-releasing properties, but the O atom of the methoxy group was electron-withdrawing, thereby influencing the bond lengths and angles of the dithiolane ring. The structure determination of the compound was undertaken to understand the effects of the methoxybicyclo-octene system and to compare the results with those found in 1,2,3,4- tetrahydrocarbazole-1-spiro-2'-[1,3]dithiolane.

Yazar Gültekin Z.
Adams H.
Hökelek T.
Yayın Türü Article
Tek Biçim Adres https://hdl.handle.net/20.500.12628/3808
Tek Biçim Adres 10.1107/S1600536803012005
Koleksiyonlar Araştırma Çıktıları | WoS | Scopus | TR-Dizin | PubMed | SOBİAD
Scopus İndeksli Yayınlar Koleksiyonu
Dergi Adı Acta Crystallographica Section E: Structure Reports Online
Dergi Cilt Bilgisi 59
Dergi Sayısı 7
Sayfalar o926 - o928
Yayın Yılı 2003
Eser Adı
[dc.title]
(1RS,4RS)-1-Methoxyspiro[bicyclo[2.2.2]oct-5-ene-2,2'-[1', 3']dithiolane]
Yazar
[dc.contributor.author]
Gültekin Z.
Yazar
[dc.contributor.author]
Adams H.
Yazar
[dc.contributor.author]
Hökelek T.
Yayın Yılı
[dc.date.issued]
2003
Yayın Türü
[dc.type]
article
Özet
[dc.description.abstract]
The preparation of (1RS,4RS)1-Methoxyspiro[bicyclo[2.2.2]oct-5-ene-2, 2'-[1',3 ']dithiolane] compound by a literature method was shown. The compound consists of a five-membered dithiolane ring with a methoxybicyclooctene spiro-fused at the 2-position. It was observed that the S atom of the dithiolane ring have electron-releasing properties, but the O atom of the methoxy group was electron-withdrawing, thereby influencing the bond lengths and angles of the dithiolane ring. The structure determination of the compound was undertaken to understand the effects of the methoxybicyclo-octene system and to compare the results with those found in 1,2,3,4- tetrahydrocarbazole-1-spiro-2'-[1,3]dithiolane.
Kayıt Giriş Tarihi
[dc.date.accessioned]
2019-12-23
Açık Erişim Tarihi
[dc.date.available]
2019-12-23
Yayın Dili
[dc.language.iso]
eng
Haklar
[dc.rights]
info:eu-repo/semantics/closedAccess
ISSN
[dc.identifier.issn]
1600-5368
İlk Sayfa Sayısı
[dc.identifier.startpage]
o926
Son Sayfa Sayısı
[dc.identifier.endpage]
o928
Dergi Adı
[dc.relation.journal]
Acta Crystallographica Section E: Structure Reports Online
Dergi Sayısı
[dc.identifier.issue]
7
Dergi Cilt Bilgisi
[dc.identifier.volume]
59
Tek Biçim Adres
[dc.identifier.uri]
https://dx.doi.org/10.1107/S1600536803012005
Tek Biçim Adres
[dc.identifier.uri]
https://hdl.handle.net/20.500.12628/3808
Görüntülenme Sayısı ( Şehir )
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Görüntülenme Sayısı ( Zaman Dağılımı )
Görüntülenme
11
09.12.2022 tarihinden bu yana
İndirme
1
09.12.2022 tarihinden bu yana
Son Erişim Tarihi
17 Nisan 2024 11:56
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dithiolane compound literature effects lengths 4RS)1-Methoxyspiro[bicyclo[2 angles structure determination undertaken understand system methoxybicyclo-octene thereby compare results tetrahydrocarbazole-1-spiro-2 3]dithiolane influencing electron-withdrawing 2-position consists five-membered ]dithiolane] methoxybicyclooctene spiro-fused 2]oct-5-ene-2 method observed preparation electron-releasing properties methoxy
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