Synthesis and crystal structure of diaquatetra(5-methyl-1, 2-oxazol-3-amine)iron(II) perchlorate

A new monomeric iron(II) complex of 5-methyl-1,2-oxazol-3-amine(moxa) has been synthesized and structurally characterized. Fe(II) atom is in a distorted octahedral environment with four ring N atoms of the oxazol and two water ligands. Complex molecules and uncoordinated oxazol ligands are linked together by hydrogen bonding. This complex is diamagnetic at different temperatures and no spin-crossover was observed. Magnetic susceptibility measurement was performed by Evans method in solution. IR and UV-vis spectrum of the complex was measured to investigate the solution behavior of the complex. The space group is P¯ (No. 2), with a = 7.4137(2), b = 10.9395(3), c = 13.5284(3) Å, ? = 67.146(1), ß = 88.565(1), ? = 78.556(1)o, V = 989.31(4) Å3, and Z = 1.

Yazar Baran Y.
Linert W.
Yayın Türü Article
Tek Biçim Adres https://hdl.handle.net/20.500.12628/7751
Tek Biçim Adres 10.1023/A:1015651422973
Konu Başlıkları Fe(II)
Oxazol derivatives
Susceptibility
Koleksiyonlar Araştırma Çıktıları | WoS | Scopus | TR-Dizin | PubMed | SOBİAD
Scopus İndeksli Yayınlar Koleksiyonu
Dergi Adı Journal of Chemical Crystallography
Dergi Cilt Bilgisi 31
Dergi Sayısı 07.Aug
Sayfalar 369 - 372
Yayın Yılı 2001
Eser Adı
[dc.title]
Synthesis and crystal structure of diaquatetra(5-methyl-1, 2-oxazol-3-amine)iron(II) perchlorate
Yazar
[dc.contributor.author]
Baran Y.
Yazar
[dc.contributor.author]
Linert W.
Yayın Yılı
[dc.date.issued]
2001
Yayın Türü
[dc.type]
article
Özet
[dc.description.abstract]
A new monomeric iron(II) complex of 5-methyl-1,2-oxazol-3-amine(moxa) has been synthesized and structurally characterized. Fe(II) atom is in a distorted octahedral environment with four ring N atoms of the oxazol and two water ligands. Complex molecules and uncoordinated oxazol ligands are linked together by hydrogen bonding. This complex is diamagnetic at different temperatures and no spin-crossover was observed. Magnetic susceptibility measurement was performed by Evans method in solution. IR and UV-vis spectrum of the complex was measured to investigate the solution behavior of the complex. The space group is P¯ (No. 2), with a = 7.4137(2), b = 10.9395(3), c = 13.5284(3) Å, ? = 67.146(1), ß = 88.565(1), ? = 78.556(1)o, V = 989.31(4) Å3, and Z = 1.
Kayıt Giriş Tarihi
[dc.date.accessioned]
2019-12-23
Açık Erişim Tarihi
[dc.date.available]
2019-12-23
Yayın Dili
[dc.language.iso]
eng
Konu Başlıkları
[dc.subject]
Fe(II)
Konu Başlıkları
[dc.subject]
Oxazol derivatives
Konu Başlıkları
[dc.subject]
Susceptibility
Haklar
[dc.rights]
info:eu-repo/semantics/closedAccess
ISSN
[dc.identifier.issn]
1074-1542
Sponsor YAYINCI
[dc.description.sponsorship]
This work was supported by the Austrian Student Exchange Service and the Institution of Inorganic Chemistry of Vienna Technical University.
İlk Sayfa Sayısı
[dc.identifier.startpage]
369
Son Sayfa Sayısı
[dc.identifier.endpage]
372
Dergi Adı
[dc.relation.journal]
Journal of Chemical Crystallography
Dergi Sayısı
[dc.identifier.issue]
07.Aug
Dergi Cilt Bilgisi
[dc.identifier.volume]
31
Tek Biçim Adres
[dc.identifier.uri]
https://dx.doi.org/10.1023/A:1015651422973
Tek Biçim Adres
[dc.identifier.uri]
https://hdl.handle.net/20.500.12628/7751
Görüntülenme Sayısı ( Şehir )
Görüntülenme Sayısı ( Ülke )
Görüntülenme Sayısı ( Zaman Dağılımı )
Görüntülenme
98
09.12.2022 tarihinden bu yana
İndirme
1
09.12.2022 tarihinden bu yana
Son Erişim Tarihi
14 Temmuz 2024 10:53
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Tıklayınız
complex ligands solution oxazol behavior investigate measured spectrum UV-vis 4137(2) 565(1) 556(1)o 146(1) 5284(3) 9395(3) method spin-crossover performed Fe(II) environment octahedral distorted characterized structurally synthesized 2-oxazol-3-amine(moxa) 5-methyl-1 iron(II) monomeric measurement susceptibility Magnetic observed temperatures different
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