Synthesis of B/P/N Containing Flame-Retardant Additives and UV Curable Hybrid Coating Applications

The aim of this study is to synthesize flame-retardant additive by using B/P/N and to investigate this additive's performance in the ultraviolet (UV) curable system. Therefore, in the first stage, borate ester (triethanolamine borate, TEAB) was synthesized by the reaction of boric acid and triethanolamine. In the second stage, phosphate salt of borate ester (triethanolamine borate polyphosphoric acid, TEAB-PPA) was synthesized by the reaction of borate ester (TEAB), which synthesized in the first stage and PPA. Thermal stability and flammability of the samples were evaluated by thermal gravimetric analysis, differential scanning calorimetry, and limiting oxygen index. The samples were characterized with the following analyses: Fourier transform infrared, nuclear magnetic resonance, UV transmittance, gel content, water absorption capacity, and stress–strain test. Hydrophilicity of the samples was determined by the contact angle measurements. Moreover, the surface morphology of the samples was investigated by a scanning electron microscopy–energy dispersive spectrometer mapping. The obtained results prove that boron, nitrogen, and phosphorus increased the flame retardancy property of the synthesized additive and suggest desired flame retardancy using various resins and different ratio of additives. © 2015 Wiley Periodicals, Inc.

Dergi Adı Advances in Polymer Technology
Dergi Cilt Bilgisi 36
Dergi Sayısı 4
Sayfalar 517 - 524
Yayın Yılı 2017
Eser Adı
[dc.title]
Synthesis of B/P/N Containing Flame-Retardant Additives and UV Curable Hybrid Coating Applications
Yazar
[dc.contributor.author]
Ocakoglu M.
Yazar
[dc.contributor.author]
Şen F.
Yazar
[dc.contributor.author]
Kahraman M.V.
Yayın Yılı
[dc.date.issued]
2017
Yayıncı
[dc.publisher]
John Wiley and Sons Inc.
Yayın Türü
[dc.type]
article
Özet
[dc.description.abstract]
The aim of this study is to synthesize flame-retardant additive by using B/P/N and to investigate this additive's performance in the ultraviolet (UV) curable system. Therefore, in the first stage, borate ester (triethanolamine borate, TEAB) was synthesized by the reaction of boric acid and triethanolamine. In the second stage, phosphate salt of borate ester (triethanolamine borate polyphosphoric acid, TEAB-PPA) was synthesized by the reaction of borate ester (TEAB), which synthesized in the first stage and PPA. Thermal stability and flammability of the samples were evaluated by thermal gravimetric analysis, differential scanning calorimetry, and limiting oxygen index. The samples were characterized with the following analyses: Fourier transform infrared, nuclear magnetic resonance, UV transmittance, gel content, water absorption capacity, and stress–strain test. Hydrophilicity of the samples was determined by the contact angle measurements. Moreover, the surface morphology of the samples was investigated by a scanning electron microscopy–energy dispersive spectrometer mapping. The obtained results prove that boron, nitrogen, and phosphorus increased the flame retardancy property of the synthesized additive and suggest desired flame retardancy using various resins and different ratio of additives. © 2015 Wiley Periodicals, Inc.
Kayıt Giriş Tarihi
[dc.date.accessioned]
2019-12-23
Açık Erişim Tarihi
[dc.date.available]
2019-12-23
Yayın Dili
[dc.language.iso]
eng
Konu Başlıkları
[dc.subject]
Borate esters
Konu Başlıkları
[dc.subject]
Flame retardance
Konu Başlıkları
[dc.subject]
Morphology
Konu Başlıkları
[dc.subject]
Thermal properties
Konu Başlıkları
[dc.subject]
UV curable
Haklar
[dc.rights]
info:eu-repo/semantics/closedAccess
ISSN
[dc.identifier.issn]
0730-6679
İlk Sayfa Sayısı
[dc.identifier.startpage]
517
Son Sayfa Sayısı
[dc.identifier.endpage]
524
Dergi Adı
[dc.relation.journal]
Advances in Polymer Technology
Dergi Sayısı
[dc.identifier.issue]
4
Dergi Cilt Bilgisi
[dc.identifier.volume]
36
Tek Biçim Adres
[dc.identifier.uri]
https://dx.doi.org/10.1002/adv.21638
Tek Biçim Adres
[dc.identifier.uri]
https://hdl.handle.net/20.500.12628/7762
Görüntülenme Sayısı ( Şehir )
Görüntülenme Sayısı ( Ülke )
Görüntülenme Sayısı ( Zaman Dağılımı )
Görüntülenme
36
09.12.2022 tarihinden bu yana
İndirme
1
09.12.2022 tarihinden bu yana
Son Erişim Tarihi
11 Nisan 2024 23:57
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Tıklayınız
borate samples synthesized additive retardancy (triethanolamine reaction scanning contact investigated morphology surface Moreover measurements suggest electron determined Hydrophilicity stress–strain capacity absorption content Periodicals dispersive microscopy–energy property various resins different additives increased desired phosphorus nitrogen results
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