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Simultaneous determination of iprodione, procymidone, and chlorflurenol in lake water and wastewater matrices by GC-MS after multivariate optimization of binary dispersive liquid-liquid microextraction

Özdoğan, Nizamettin | Kapukıran, Fatih | Mutluoğlu, Gülşen | Chormey, Dotse Selali | Bakırdere, Sezgin

Article | 2018 | Environmental Monitoring and Assessment190 ( 10 )

This study reports the optimization of a binary dispersive liquid-liquid microextraction method for the determination of iprodione, procymidone, and chlorflurenol by gas chromatography mass spectrometry. The study was aimed at using two extraction solvents to increase the extraction efficiency of all analytes. The binary solvents recorded results higher than the mono-solvents. After examining the effects of main experimental parameters and their interactions by analysis of variance, 200 µL of binary mixture (dichloromethane and 1,2-dichloroethane), 2.5 mL of ethanol, and 15 s vortex were obtained as optimum parameters. The detection . . . and quantification limits calculated for the analytes were found to be between 0.30–1.6 and 1.0–5.3 ng/mL, respectively. Enhancement in detection power calculated as a ratio of the binary extraction detection limit to the detection limit of direct GC-MS analysis was 105-, 214-, and 233-fold for chlorflurenol, iprodione, and procymidone, respectively. In order to check the accuracy of the developed method, recovery study was performed. Water sampled from a lake and two wastewater samples from treatment facilities were spiked at two concentrations, and the percent recovery calculated for the samples ranged between 87 and 116%. These results confirmed the suitability of the method to real samples for accurate determination of the analytes at trace levels. © 2018, Springer Nature Switzerland AG Daha fazlası Daha az

Magnetic cobalt particle–assisted solid phase extraction of tellurium prior to its determination by slotted quartz tube-flame atomic absorption spectrophotometry

Özdoğan, Nizamettin | Kapukıran, Fatih | Öztürk Er, Elif | Bakırdere, Sezgin

Article | 2019 | Environmental Monitoring and Assessment191 ( 6 )

The emergence of magnetic materials has opened up doors to numerous applications including their use as sorbents for preconcentration of trace elements. Magnetic materials exhibit many unique advantages in sample preparation such as easy separation from the sample, high preconcentration factor, and short operation period. In the present study, magnetic cobalt material was synthesized, characterized, and used as an effective sorbent in a solid phase extraction process. Experimental variables of the extraction process including pH and volume of buffer solution, eluent concentration and volume, mixing type and period, and sorbent amoun . . .t were optimized to achieve maximum extraction efficiency. Instrumental variables of flame atomic absorption spectrophotometry and the type of slotted quartz tube were also investigated. Under the optimum conditions, the combined method provided a wide linear range between 50 and 200 ng/mL with detection and quantification limits of 15.4 ng/mL and 51.3 ng/mL, respectively. Relative standard deviations of the proposed method were less than 5.0% and a high enrichment factor of 86.7 was obtained. The proposed method was successfully applied to soil samples for the determination of trace tellurium. © 2019, Springer Nature Switzerland AG Daha fazlası Daha az

Landslide susceptibility mapping in an area of underground mining using the multicriteria decision analysis method

Arca D. | Kutoğlu, Hakan Şenol | Becek K.

Article | 2018 | Environmental Monitoring and Assessment190 ( 12 )

Landslides are geomorphological phenomena that affect anthropogenic and natural features on the Earth’s surface. Many previous studies have identified several factors that have contributed to landslides. Among these factors are physical characteristics, such as slope, aspect, and land cover, of Earth’s surface. Moreover, landslides can be triggered by human activities such as underground mining. This study aims to identify landslide susceptibility areas by analyzing landslide-related factors, including land subsidence triggered by underground mining. The area of interest was Kozlu, Turkey, where underground mining has been in progre . . .ss for the past 100 years. Thus, to identify landslide risk zones, the multicriteria decision analysis method, together with the analytical hierarchy method, was used. The datasets included were topography, land cover, geological settings, and mining-induced land subsidence. The spatial extent of land subsidence was estimated using a previously published model. A landslide susceptibility map (LSM) was developed using a purposely developed GIS-based software. The results were compared with a terrain deformation map, which was developed in a separate study using the differential synthetic aperture radar interferometry (DInSAR) technique. The results showed a substantial correlation between the LSM and DInSAR map. Furthermore, it was found that ~ 88% of the very high and high landslide risk areas coincided with location of the past landslide events. These facts suggest that the algorithm and data sources used were sufficient to produce a sufficiently accurate LSM, which may be used for various purposes such as urban planning. © 2018, The Author(s) Daha fazlası Daha az

Modeling land use/land cover change using remote sensing and geographic information systems: case study of the Seyhan Basin, Turkey

Zadbagher E. | Becek K. | Berberoglu S.

Article | 2018 | Environmental Monitoring and Assessment190 ( 8 )

Land use and land cover (LULC) changes affect several natural environmental factors, including soil erosion, hydrological balance, biodiversity, and the climate, which ultimately impact societal well-being. Therefore, LULC changes are an important aspect of land management. One method used to analyze LULC changes is the mathematical modeling approach. In this study, Cellular Automata and Markov Chain (CA-MC) models were used to predict the LULC changes in the Seyhan Basin in Turkey that are likely to occur by 2036. Satellite multispectral imagery acquired in the years 1995, 2006, and 2016 were classified using the object-based class . . .ification method and used as the input data for the CA-MC model. Subsequently, the post-classification comparison technique was used to determine the parameters of the model to be simulated. The Markov Chain analyses and the multi-criteria evaluation (MCE) method were used to produce a transition probability matrix and land suitability maps, respectively. The model was validated using the Kappa index, which reached an overall level of 77%. Finally, the LULC changes were mapped for the year 2036 based on transition rules and a transition area matrix. The LULC prediction for the year 2036 showed a 50% increase in the built-up area class and a 7% decrease in the open spaces class compared to the LULC status of the reference year 2016. About an 8% increase in agricultural land is also likely to occur in 2036. About a 4% increase in shrub land and a 5% decrease in forest areas are also predicted. © 2018, Springer Nature Switzerland AG Daha fazlası Daha az

Evaluation of spatio-temporal variability in Land Surface Temperature: A case study of Zonguldak, Turkey

Sekertekin A. | Kutoglu S.H. | Kaya S.

Article | 2016 | Environmental Monitoring and Assessment188 ( 1 ) , pp.1 - 15

The aim of this study is to analyze spatio-temporal variability in Land Surface Temperature (LST) in and around the city of Zonguldak as a result of the growing urbanization and industrialization during the last decade. Three Landsat 5 data and one Landsat 8 data acquired on different dates were exploited in acquiring LST maps utilizing mono-window algorithm. The outcomes obtained from this study indicate that there exists a significant temperature rise in the region for the time period between 1986 and 2015. Some cross sections were selected in order to examine the relationship between the land use and LST changes in more detail. T . . .he mean LST difference between 1986 and 2015 in ERDEMIR iron and steel plant (6.8 °C), forestland (3 °C), city and town centers (4.2 °C), municipal rubbish tip (-3.9 °C), coal dump site (12.2 °C), and power plants’ region (7 °C) were presented. In addition, the results indicated that the mean LST difference between forestland and city centers was approximately 5 °C, and the difference between forestland and industrial enterprises was almost 8 °C for all years. Spatio-temporal variability in LST in Zonguldak was examined in that study and due to the increase in LST, policy makers and urban planners should consider LST and urban heat island parameters for sustainable development. © 2015, Springer International Publishing Switzerland Daha fazlası Daha az

The acquisition of impervious surface area from LANDSAT 8 satellite sensor data using urban indices: a comparative analysis

Sekertekin A. | Abdikan S. | Marangoz A.M.

Article | 2018 | Environmental Monitoring and Assessment190 ( 7 ) , pp.1 - 15

Rapid and irregular urbanization is an essential issue in terms of environmental assessment and management. The dynamics of landscape patterns should be observed and analyzed by local authorities for a sustainable environment. The aim of this study is to determine which spectral urban index, originated from old Landsat missions, represents impervious area better when new generation Earth observation satellite Landsat 8 data are used. Two datasets of Landsat 8, acquired on 2 September 2013 and 10 September 2016, were utilized to investigate the consistency of the results. In this study, commonly used urban indices namely normalized d . . .ifference built-up index (NDBI), index-based built-up index (IBI), urban index (UI), and enhanced built-up and bareness index (EBBI) were utilized to extract impervious areas. The accuracy assessment of urban indices was conducted by comparing the results with pan-sharpened images, which were classified using maximum likelihood classification (MLC) method. The kappa values of MLC, IBI, NDBI, EBBI, and UI for 2013 dataset were 0.89, 0.79, 0.71, 0.59, and 0.49, respectively, and the kappa values of MLC, IBI, NDBI, EBBI, and UI for 2016 dataset were 0.90, 0.78, 0.70, 0.56, and 0.47, respectively. In addition, area information was extracted from indices and classified images, and the obtained outcomes showed that IBI presented better results than the other urban indices, and UI extracted impervious areas worse than the other indices in both selected cases. Consequently, Landsat 8 satellite data can be considered as an important source to extract and monitor impervious surfaces for the sustainable development of cities. © 2018, Springer International Publishing AG, part of Springer Nature Daha fazlası Daha az

Biomonitoring of polycyclic aromatic hydrocarbons in urban and industrial environments of the Western Black Sea Region, Turkey

Çabuk, Hasan | Kılıç, Muhammet Samet | Ören, Muhammet

Article | 2014 | Environmental Monitoring and Assessment186 ( 3 ) , pp.1515 - 1524

This research was carried out in the cities of Zonguldak and Eregli, which have been characterized as urban and industrial environments of the Western Black Sea Region, Turkey, in order to assess the contamination of polycyclic aromatic hydrocarbons (PAHs) using mosses as biomonitors. The methodology involved the collection of moss samples (Hypnum cupressiforme), ultrasonic extraction with dichloromethane, cleanup using silica gel and analysis by liquid chromatography with ultraviolet detection. The total PAH concentrations ranged from 78.1 to 1693.5 ng g -1 in Zonguldak and from 15.2 to 275.1 ng g -1 in Eregli. The total PAH concen . . .tration in Eregli was about six times lower than that in Zonguldak, revealing the importance of switching from coal to natural gas in residential heating. The diagnostic ratios and the correlation analysis have indicated that coal combustion and traffic emissions were the major PAH sources at both sites. The contour maps were constructed for the determination of spatial distributions of total PAHs, and it was shown for Zonguldak as well as for Eregli that the PAH pollution was much more predominant in highly populated regions. Moving away from the city centres, a gradual decrease in PAH pollution rates was observed. © 2013 Springer Science+Business Media Daha fazlası Daha az

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