Hazer, Baki | Hirao, Akira | Volga, Cüneyt

Article | 1999 | Macromolecular Chemistry and Physics200 ( 1 ) , pp.71 - 76

In order to synthesize benzoyl peroxide functionalized polystyrene (PSt), polyisoprene (PI) and poly(methyl methacrylate) (PMMA), anionic living PSt, PI, and PMMA were allowed to react with an excess amount of 4-(bromomethyl)benzoyl tert-butyl peroxide (BMtB) or bis[3,5-bis(bromomethyl)benzoyl] peroxide (BDBP) in tetrahydrofuran (THF) at -78°C. The results indicate that coupling reactions leading to dimers are significant during the reaction. Dimer formation was avoided when the living polystyrene was modified to the alcoholate anion by reaction with ethylene oxide (EO). © Wiley-VCH Verlag GmbH, 1999.

Menteş, Ayger | Sarbay, Mithat | Hazer, Baki | Arslan, Hülya

Article | 2005 | Applied Organometallic Chemistry19 ( 1 ) , pp.76 - 80

Mo(CO)6 was reacted with the Schiff base ligand obtained by condensation reaction of 2-acetyl- or benzoylpyridine with poly(propylene glycol)bis(2-aminopropyl ether) to obtain polymeric, dinuclear metal tetracarbonyl compounds. The long-chain Schiff base complexes are highly soluble even in non-polar solvents such as petroleum ether, diethyl ether and n-hexane. These complexes, as free-radical initiators, afforded methyl methacrylate polymerization in chlorinated solvents. Copyright © 2004 John Wiley & Sons, Ltd.

Korkut, Şeyda | Kılıç, Muhammet Samet | Hazer, Baki

Article | 2019 | Asia-Pacific Journal of Chemical Engineering14 ( 6 ) , pp.76 - 80

A copolymer poly(methyl methacrylate-co-vinylferrocene) was synthesized and used for the first time in a biofuel cell design. Bioanaode enzyme glucose oxidase and biocathode enzyme bilirubin oxidase were physically immobilized onto the copolymer-modified electrodes. Characterization studies were conducted by scanning electron microscopy, carbon-13, fourier transform infrared and hydrogen-1 nuclear magnetic resonance, and cyclic voltammograms. The designed biofuel cell was operated with linear sweep voltammetry. The maximum current was at 45°C with 120 µg of polymer amount. An improved power density of 323 µW cm-2 that is higher than . . . other ferrocene-based fuel cells was obtained with 10-mM glucose at 0.4 V with the designed bioanode. © 2019 John Wiley & Sons Ltd Daha fazlası Daha az

Macit, Hülya | Hazer, Baki

Article | 2004 | Journal of Applied Polymer Science93 ( 1 ) , pp.219 - 226

Combination of cationic, redox free radical, and thermal free radical polymerizations was performed to obtain linear and star polytetramethylene oxide (poly-THF)-polymethyl methacrylate (PMMA)/polystyrene (PSt) multiblock copolymers. Cationic polymerization of THF was initiated by the mixture of AgSbF6 and bis(4,4' bromo-methyl benzoyl) peroxide (BBP) or bis (3,5,3',5' dibromom-ethyl benzoyl) peroxide (BDBP) at 20°C to obtain linear and star poly-THF initiators with MW varying from 7,500 to 59,000 Da. Poly-THF samples with hydroxyl ends were used in the methyl methacrylate (MMA) polymerization in the presence of Ce(IV) salt at 40°C . . .to obtain poly(THF-b-MMA) block copolymers containing the peroxide group in the middle. Poly(MMA-b-THF) linear and star block copolymers having the peroxide group in the chain were used in the polymerization of methyl methacrylate (MMA) and styrene (St) at 80°C to obtain PMMA-b-PTHF-b-PMMA and PMMA-b-PTHF-PSt linear and star multiblock copolymers. Polymers obtained were characterizated by GPC, FT-IR, DSC, TGA, 1H-NMR, and 13C-NMR techniques and the fractional precipitation method. © 2004 Wiley Periodicals, Inc Daha fazlası Daha az

Macit, Hülya | Hazer, Baki | Arslan, Hülya | Noda, Isao

Article | 2009 | Journal of Applied Polymer Science111 ( 5 ) , pp.2308 - 2317

A new and promising method for the diversification of microbial polyesters based on chemical modifications is introduced. Poly(3-hydroxy alkanoate)-g-(poly(tetrahydrofuran)-b-poly(methyl methacrylate)) (PHAg-(PTHF-b-PMMA)) multigraft copolymers were synthesized by the combination of cationic and free radical polymerization. PHA-g-PTHF graft copolymer was obtained by the cationic polymerization of THF initiated by the carbonium cations generated from the chlorinated PHAs, poly(3-hydroxybutyrate-co-3- hydroxyvalerate) (PHBV), and poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHx) in the presence of AgSbF 6. Therefore, PHA-g-PTHF gr . . .aft copolymers with hydroxyl ends were produced. In the presence of Ce +4 salt, these hydroxyl ends of the graft copolymer can initiate the redox polymerization of MMA to obtain PHA-g-(PTHF-b-PMMA) multigraft copolymer. Polymers obtained were purified by fractional precipitation. In this manner, their ?-values (volume ratio of nonsolvent to the solvent) were also determined. Their molecular weights were determined by GPC technique. The structures were elucidated using 1H-NMR and FTIR spectroscopy. Thermal analyses of the products were carried out using differential scanning calorimeter (DSC) and thermogravimetric analysis (TGA). © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 111: 2308-2317, 2009 Daha fazlası Daha az

Öztürk, Temel | Göktaş, Melahat | Hazer, Baki

Article | 2010 | Journal of Applied Polymer Science117 ( 3 ) , pp.1638 - 1645

One-step synthesis of star copolymers by reversible addition-fragmentation chain transfer (RAFT) and ring-opening polymerization (ROP) by using a novel dual initiator is reported. Triarm block copolymers comprising one polystyrene (or polyacrylamide) arm and two poly(b-butyrolactone) arms were synthesized in one-step by simultaneous RAFT polymerization of styrene (St) (or acrylamide, designated as AAm) and ROP of b-butyrolactone (BL) in the presence of a novel trifunctional initiator, 1,2-propanediol ethyl xanthogenate (RAFT-ROP agent). This dual initiator was obtained through the reaction of 3-chloro-1,2- propanediol with the potas . . .sium salt of ethyl xanthogenate. The principal parameters such as monomer concentration, initiator concentration, and polymerization time that affect the one-step polymerization reaction were evaluated. The characterization of the products was achieved using Fourier-transform infrared spectroscopy (FTIR), 1H-nuclear magnetic resonance (1HNMR),13C-nuclear magnetic resonance ( 13C-NMR), Gas chromatography-mass spectrometry (GC-MS), gel-permeation chromatography (GPC), thermogravimetric analysis (TGA), and fractional precipitation (c) techniques. VC 2010 Wiley Periodicals, Inc Daha fazlası Daha az

Allı, Sema | Allı, Abdulkadir | Hazer, Baki

Article | 2012 | Journal of Applied Polymer Science124 ( 1 ) , pp.536 - 548

Macromonomer initiators behave as macro cross-linkers, macro initiators, and macromonomers to obtain branched and cross-linked block/graft copolymers. A series of new macromonomer initiators for atom transfer radical polymerization (MIM-ATRP) based on polyethylene glycol (M n = 495D, 2203D, and 4203D) (PEG) were synthesized by the reaction of the hydroxyl end of mono-methacryloyl polyethylene glycol with 2-bromo propanoyl chloride, leading to methacryloyl polyethylene glycol 2-bromo propanoyl ester. Poly (ethylene glycol) functionalized with methacrylate at one end was reacted with 2-bromopropionyl chloride to form a macromonomeric . . .initiator for ATRP. ATRP was found to be a more controllable polymerization method than conventional free radical polymerization in view of fewer cross-linked polymers and highly branched polymers produced from macromonomer initiators as well. In another scenario, ATRP of N-isopropylacrylamide (NIPAM) was initiated by MIM-ATRP to obtain PEG-b-PNIPAM branched block/graft copolymers. Thermal analysis, FTIR, 1H NMR, TEM, and SEM techniques were used in the characterization of the products. They had a thermo-responsive character and exhibited volume phase transition at â 36°C. A plasticizer effect of PEG in graft copolymers was also observed, indicating a lower glass transition temperature than that of pure PNIPAM. Homo and copolymerization kinetics were also evaluated. © 2011 Wiley Periodicals, Inc Daha fazlası Daha az

Allı, Abdulkadir | Allı, Sema | Becer, C. Remzi | Hazer, Baki

Article | 2016 | European Journal of Lipid Science and Technology118 ( 2 ) , pp.279 - 287

Polymeric linoleic asit graft copolymers were synthesized via a nitroxide-mediated radical polymerization (NMRP) method in the presence of 2,2-6,6-tetramethylpiperidinyl-1-oxy (TEMPO). For this purpose, PLina-ox was exposed to polymerization with styrene (Sty) or Sty and pentafluorostyrene (F5Sty) in the presence of TEMPO by NMRP method in order to obtain PLina-g-PSty and PLina-g-PF5Sty-g-PSty graft copolymers with controlled structure and low polydispersity. Chain extension study was evaluated. Principal parameters, such as monomer concentration, initiator concentration, and polymerization time, which effect the polymerization reac . . .tions, were evaluated. The products thus obtained were well characterized by 1H NMR, GPC, and 19F NMR measurements. Practical application: We report for the first time the synthesis of PLina-g-PSty and PLina-g-PSty-g-PF5Sty graft copolymers in the presence of TEMPO. NMRP reactions were performed in the presence of TEMPO in order to obtain graft copolymers with controlled molecular weight and polydispersity. Chain-extension reactions were also successfully carried out because of the activation of TEMPO terminated chain ends of graft copolymers. Pure linoleic acid was auto-oxidized under daylight and air oxygen, yielding peroxidized PLina (PLina-ox). PLina-ox has been used in the polymerization of styrene (Sty) or copolymerization of Sty and pentafluorostyrene (F5Sty). © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Daha fazlası Daha az

Kılıç, Muhammet Samet | Korkut, Şeyda | Hazer, Baki

Article | 2017 | Electroanalysis29 ( 10 ) , pp.2377 - 2384

Newly synthesized poly(styrene-g-oleic amide) was coated onto a rhodium nanoparticle modified glassy carbon (GC) surface for the fabrication of horseradish peroxidase based biosensor used for hydrogen peroxide detection. The rhodium modifed electrode presented ten times higher signal than unmodified electrode even at low elecrtroactive enzyme quantity by enhancing the electron transfer rate at the applied potential of -0.65 V. The biosensor designed by under the optimized rhodium electrodeposition time exhibited a fast response less than 5 s, an excellent operational stability with a relative standard deviation of 0.6 % (n=6), an ac . . .curacy of 96 % and a large linear range between 50 µM and 120 mM for hydrogen peroxide. Detection limit and the sensitivity parameters were calculated to be 44 µM and 57 µA mM-1 cm-2, respectively by preserving its entire initial response up to the 15 days, while only 20 % of its initial response was lost at the end of one month. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinhei Daha fazlası Daha az

Kolsal, Ebru | Tekin, İshak Özel | Pişkin, Etem | Aydemir, Cumhur | Akyüz, Mehmet | Çabuk, Hasan | Eldes, Nilüfer | Numanoğlu, Kemal Varın

Article | 2009 | Journal of Clinical Apheresis24 ( 1 ) , pp.21 - 24

Tricyclic antidepressant poisoning is one of the most common causes of serious intoxication. Here, we report a 2-year-old girl with severe amitriptyline (70 mg/kg) intoxication. She was in comatose, had generalized tonic clonic seizure, ventricular tachycardia, and wide QRS complexes. Although she did not respond to classical therapies, very good clinical response to plasmapheresis was obtained and she developed no complications. Thus, plasmapheresis may be an effective treatment modality in poisoning with drugs, which bind to plasma proteins with high affinity. © 2009 Wiley-Liss, Inc.

Erduranlı, Haydar | Hazer, Baki | Borcaklı, Mehlika

Conference Object | 2008 | Macromolecular Symposia269 ( 1 ) , pp.161 - 169

Chemical modification is useful to diversify poly(3-hydroxyalkanoate)s, for medical and industrial applications. In this manner, transesterification reactions of poly(3-hydroxy butyrate) were carried out under reflux condition of 1,2-dichlorobenzene in the presence of 1,4-butane diol, poly(ethyleneglycol) bis(2-aminopropyl ether) with molecular weights of 1000 and 2000, poly(ethylene glycol)methacrylate or glycerol at 180°C. Addition reactions of bromine and -SH groups of 3-mercaptopropionic acid to the double bond of poly(3-hydroxy-io-undecenoate) were also carried out. Functionalized poly(3-hydroxyalkanoate)s were characterized us . . .ing 1H NMR, FTIR, GPC and thermal analysis techniques. Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA Daha fazlası Daha az

Öztürk, Temel | Yılmaz-Savaşkan, Sevil | Hazer, Baki | Menceloğlu, Yusuf Z.

Article | 2010 | Journal of Polymer Science, Part A: Polymer Chemistry48 ( 6 ) , pp.1364 - 1373

This article reports the synthesis of the block and graft copolymers using peroxygen-containing poly(methyl methacrylate) (poly-MMA) as a macroinitiator that was prepared from the atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) in the presence of bls(4,4'-bromomethyl benzoyl peroxide) (BBP). The effects of reaction temperatures on the ATRP system were studied in detail. Kinetic studies were carried out to investigate controlled ATRP for BBP/CuBr/bpy initiating system with MMA at 40 °C and free radical polymerization of styrene (S) at 80 °C The plots of In ([M o]/[Mt]) versus reaction time are linear, corresp . . .onding to first-order kinetics. Poly-MMA initiators were used In the bulk polymerization of S to obtain poly (MMA-b-S) block copolymers. Poly-MMA initiators containing undecomposed peroygen groups were used for the graft copolymerization of polybutadiene (PBd) and natural rubber (RSS-3) to obtain crosslinked poly (MMA-g-PBd) and poly(MMAg-RSS-3) graft copolymers. Swelling ratio values (q v) of the graft copolymers in CHCl3 were calculated. The characterizations of the polymers were achieved by Fourier-transform infrared spectroscopy (FTIR), 1H-nuclear magnetic resonance (1H NMR), gelpermeation chromatography (GPC), differential scanning calorimetry (DSC), thermogravimetric analysis, scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), and the fractional precipitation (?) techniques. © 2010 Wiley Periodicals, Inc Daha fazlası Daha az