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Relationship among chlorine dose, reaction time and bromide ions on trihalomethane formation in drinking water sources in Istanbul, Turkey

Özdemir, Kadir | Toröz, İsmail | Uyak, Vedat

Article | 2014 | Asian Journal of Chemistry26 ( 20 ) , pp.6935 - 6939

We investigate the effects of factors such as chlorine dose, reaction time and bromide ions on the formation and speciation of trihalomethanes during the chlorination of Istanbul reservoirs such as Terkos lake water, Büyükçekmece lake water and Ömerli lake water. The experimental results showed that approximately 50% of trihalomethane formation was observed in the first 4 h of reaction time in chlorinated Terkos lake water, Büyükçekmece lake water and Ömerli lake water, respectively. Trihalomethane concentrations increased with increasing chlorine dosage and reaction time. Chloroform was the major trihalomethane species forming as a . . . result of the chlorinated raw water samples. On the other hand, bromide ions play a great significant role in the distribution of trihalomethane species. The bromine and chlorine incorporation ratios were strongly related to natural organic matter precursors and bromide levels in Terkos lake water, Büyükçekmece lake water and Ömerli lake water. The percentage of bromine incorporation was much higher than that of chlorine in all chlorinated water samples Daha fazlası Daha az

Experimental investigation of trihalomethane formation and its modeling in drinking waters

Özdemir, Kadir | Yıldırım, Yılmaz | Toröz, İsmail | Uyak, Vedat

Article | 2015 | Asian Journal of Chemistry27 ( 3 ) , pp.984 - 990

This research developed models using multiple linear regression analysis for the prediction of trihalomethane formation in coagulated Istanbul drinking water sources. The power-law model (model 1), using only ?UV272 as the designed parameter, proved the best model to describe the formation of trihalomethane. The other model (model 2), included pH, total organic carbon, chlorine dosages, ultraviolet absorbance at 254 nm (UV254), specific ultraviolet absorbance (SUVA) and differential absorbance at 272 nm (?UV272). The root-meansquare error (RMSE), normalization mean square error (NMSE), regression coefficient (R2) and index of agreem . . .ent (IA) were used as statistical variables to evaluate the model performance. The better prediction results were obtained by model 1 for root-mean-square error, normalization mean square error, R2 and index of agreement as 9.14, 0.015, 0.95 and 0.99, respectively. © 2015, Chemical Publishing Co. All rights reserved Daha fazlası Daha az

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