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The synthesis of poly(?-caprolactone-co-ethylene glycol) AAB star-type amphiphilic copolymers were carried out by use of a “click” chemistry reaction to block propargyl polyethylene glycol (propargyl-PEG) to terminally azide poly(?-caprolactone) (PCL-N3). For this purpose, propargyl-PEG was synthesized by the reaction of PEGs (3000 Da, 2000 Da, 1500 Da, and 1000 Da) and propargyl chloride. Terminally chloride poly(?-caprolactone) (PCL-Cl) was carried out by means of ring-opening polymerization (ROP) of ?-caprolactone (CL) and 3-chloro-1,2-propanediol. Synthesis of PCL-N3 was obtained by the chemical interaction of PCL-Cl and sodium azide. By reacting propargyl-PEG and PCL-N3, the star-type amphiphilic copolymers were obtained. The characterization of products was accomplished by using multiple instruments including 1H-NMR, FT-IR, GPC, TGA, contact angles, and elemental analysis techniques. © 2018, © 2018 Taylor & Francis Group, LLC.
| Yazar |
Öztürk, Temel Kılıçlıoğlu, Ali Savaş, Bedrettin Hazer, Baki |
| Yayın Türü | Article |
| Tek Biçim Adres | https://hdl.handle.net/20.500.12628/7739 |
| Konu Başlıkları |
propargyl polyethylene glycol
ring-opening polymerization star-type amphiphilic copolymer terminally azide poly(?-caprolactone) “Click” chemistry |
| Koleksiyonlar |
Fakülteler Fen Edebiyat Fakültesi Kimya Bölümü Makale Koleksiyonu (Kimya Bölümü) Araştırma Çıktıları | WoS | Scopus | TR-Dizin | PubMed | SOBİAD Scopus İndeksli Yayınlar Koleksiyonu Araştırma Çıktıları | WoS | Scopus | TR-Dizin | PubMed | SOBİAD WoS İndeksli Yayınlar Koleksiyonu |
| Dergi Adı | Journal of Macromolecular Science, Part A: Pure and Applied Chemistry |
| Dergi Cilt Bilgisi | 55 |
| Dergi Sayısı | 8 |
| Sayfalar | 588 - 594 |
| Yayın Yılı | 2018 |
| Eser Adı [dc.title] | Synthesis and characterization of poly(Ɛ-caprolactone-co-ethylene glycol) star-type amphiphilic copolymers by “click” chemistry and ring-opening polymerization. |
| Yazar [dc.contributor.author] | Öztürk, Temel |
| Yazar [dc.contributor.author] | Kılıçlıoğlu, Ali |
| Yazar [dc.contributor.author] | Savaş, Bedrettin |
| Yazar [dc.contributor.author] | Hazer, Baki |
| Yayın Yılı [dc.date.issued] | 2018 |
| Yayıncı [dc.publisher] | Taylor and Francis Inc. |
| Yayın Türü [dc.type] | article |
| Özet [dc.description.abstract] | The synthesis of poly(?-caprolactone-co-ethylene glycol) AAB star-type amphiphilic copolymers were carried out by use of a “click” chemistry reaction to block propargyl polyethylene glycol (propargyl-PEG) to terminally azide poly(?-caprolactone) (PCL-N3). For this purpose, propargyl-PEG was synthesized by the reaction of PEGs (3000 Da, 2000 Da, 1500 Da, and 1000 Da) and propargyl chloride. Terminally chloride poly(?-caprolactone) (PCL-Cl) was carried out by means of ring-opening polymerization (ROP) of ?-caprolactone (CL) and 3-chloro-1,2-propanediol. Synthesis of PCL-N3 was obtained by the chemical interaction of PCL-Cl and sodium azide. By reacting propargyl-PEG and PCL-N3, the star-type amphiphilic copolymers were obtained. The characterization of products was accomplished by using multiple instruments including 1H-NMR, FT-IR, GPC, TGA, contact angles, and elemental analysis techniques. © 2018, © 2018 Taylor & Francis Group, LLC. |
| Kayıt Giriş Tarihi [dc.date.accessioned] | 2019-12-23 |
| Açık Erişim Tarihi [dc.date.available] | 2019-12-23 |
| Yayın Dili [dc.language.iso] | eng |
| Konu Başlıkları [dc.subject] | propargyl polyethylene glycol |
| Konu Başlıkları [dc.subject] | ring-opening polymerization |
| Konu Başlıkları [dc.subject] | star-type amphiphilic copolymer |
| Konu Başlıkları [dc.subject] | terminally azide poly(?-caprolactone) |
| Konu Başlıkları [dc.subject] | “Click” chemistry |
| Künye [dc.identifier.citation] | Öztürk, T., Kılıçlıoğlu, A., Savaş, B. ve Hazer, B. (2018). Synthesis and characterization of poly(Ɛ-caprolactone-co-ethylene glycol) star-type amphiphilic copolymers by “click” chemistry and ring-opening polymerization. Journal of Macromolecular Science, Part A, 55(8), 588-594. doi:10.1080/10601325.2018.1481344 |
| Haklar [dc.rights] | info:eu-repo/semantics/closedAccess |
| ISSN [dc.identifier.issn] | 1060-1325 |
| İlk Sayfa Sayısı [dc.identifier.startpage] | 588 |
| Son Sayfa Sayısı [dc.identifier.endpage] | 594 |
| Dergi Adı [dc.relation.journal] | Journal of Macromolecular Science, Part A: Pure and Applied Chemistry |
| Dergi Sayısı [dc.identifier.issue] | 8 |
| Dergi Cilt Bilgisi [dc.identifier.volume] | 55 |
| Tek Biçim Adres [dc.identifier.uri] | https://dx.doi.org/10.1080/10601325.2018.1481344 |
| Tek Biçim Adres [dc.identifier.uri] | https://hdl.handle.net/20.500.12628/7739 |