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Toxic metals from industrial wastewaters are an important environmental issue. The use of supported liquid membrane processes has gained momentum in recent years, as it allows the reuse of water and toxic metals. The aim of this study is to investigate the active transport of silver ion through a supported liquid membrane (micro-porous Fluoropore PTFE) of DC18C6 (Dicyclohexano18crown6) in toluene under various experimental conditions. For this purpose, the effects of various parameters including binary carriers, carrier concentration, feed phase concentration, the nature and concentration of stripping agents in the stripping phase and flow rates of feed and stripping phases on transport efficiency were also investigated. The maximum transport efficiency was observed at the following conditions: flow rates of 50 mL/min in both phases, 0.05 M DC18C6 in toluene as carrier solution. 50 ppm Ag(+) dissolved in 0.015 M HNO(3) as feed solution and 0.08 M Na(2)S(2)O(3) as stripping solution Optimum operation time was determined as 240 min. Under these conditions, 94% of the silver ions were transported from the feed phase to the membrane phase. However, the transport rate from the membrane phase to the stripping phase remained at approximately 81%. (C) 2010 Elsevier B.V. All rights reserved.
| Yazar |
Altın, Süreyya Yıldırım, Yılmaz Altın, Ahmet |
| Yayın Türü | Article |
| Tek Biçim Adres | https://hdl.handle.net/20.500.12628/3717 |
| Konu Başlıkları |
Supported liquid membrane
Silver Toluene DC18C6 PTFE membrane |
| Koleksiyonlar |
Fakülteler Mühendislik Fakültesi Çevre Mühendisliği Bölümü Makale Koleksiyonu (Çevre Mühendisliği Bölümü) Araştırma Çıktıları | WoS | Scopus | TR-Dizin | PubMed | SOBİAD WoS İndeksli Yayınlar Koleksiyonu |
| Dergi Adı | HYDROMETALLURGY |
| Dergi Cilt Bilgisi | 103 |
| Dergi Sayısı | 01.Apr |
| Sayfalar | 144 - 149 |
| Yayın Yılı | 2010 |
| Eser Adı [dc.title] | Transport of silver ions through a flat-sheet supported liquid membrane |
| Yazar [dc.contributor.author] | Altın, Süreyya |
| Yazar [dc.contributor.author] | Yıldırım, Yılmaz |
| Yazar [dc.contributor.author] | Altın, Ahmet |
| Yayın Yılı [dc.date.issued] | 2010 |
| Yayıncı [dc.publisher] | ELSEVIER SCIENCE BV |
| Yayın Türü [dc.type] | article |
| Özet [dc.description.abstract] | Toxic metals from industrial wastewaters are an important environmental issue. The use of supported liquid membrane processes has gained momentum in recent years, as it allows the reuse of water and toxic metals. The aim of this study is to investigate the active transport of silver ion through a supported liquid membrane (micro-porous Fluoropore PTFE) of DC18C6 (Dicyclohexano18crown6) in toluene under various experimental conditions. For this purpose, the effects of various parameters including binary carriers, carrier concentration, feed phase concentration, the nature and concentration of stripping agents in the stripping phase and flow rates of feed and stripping phases on transport efficiency were also investigated. The maximum transport efficiency was observed at the following conditions: flow rates of 50 mL/min in both phases, 0.05 M DC18C6 in toluene as carrier solution. 50 ppm Ag(+) dissolved in 0.015 M HNO(3) as feed solution and 0.08 M Na(2)S(2)O(3) as stripping solution Optimum operation time was determined as 240 min. Under these conditions, 94% of the silver ions were transported from the feed phase to the membrane phase. However, the transport rate from the membrane phase to the stripping phase remained at approximately 81%. (C) 2010 Elsevier B.V. All rights reserved. |
| Açıklama [dc.description] | WOS: 000279306100022 |
| Kayıt Giriş Tarihi [dc.date.accessioned] | 2019-12-23 |
| Açık Erişim Tarihi [dc.date.available] | 2019-12-23 |
| Yayın Dili [dc.language.iso] | eng |
| Konu Başlıkları [dc.subject] | Supported liquid membrane |
| Konu Başlıkları [dc.subject] | Silver |
| Konu Başlıkları [dc.subject] | Toluene |
| Konu Başlıkları [dc.subject] | DC18C6 |
| Konu Başlıkları [dc.subject] | PTFE membrane |
| Künye [dc.identifier.citation] | Altin, S., Yildirim, Y. ve Altin, A. (2010). Transport of silver ions through a flat-sheet supported liquid membrane. Hydrometallurgy, 103(1), 144-149. doi:10.1016/j.hydromet.2010.03.015 |
| Haklar [dc.rights] | info:eu-repo/semantics/closedAccess |
| ISSN [dc.identifier.issn] | 0304-386X |
| Sponsor YAYINCI [dc.description.sponsorship] | Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [106Y085] |
| Sponsor YAYINCI [dc.description.sponsorship] | This study was supported by The Scientific and Technological Research Council of Turkey (TUBITAK) as a research project (project no.: 106Y085). |
| İlk Sayfa Sayısı [dc.identifier.startpage] | 144 |
| Son Sayfa Sayısı [dc.identifier.endpage] | 149 |
| Dergi Adı [dc.relation.journal] | HYDROMETALLURGY |
| Dergi Sayısı [dc.identifier.issue] | 01.Apr |
| Dergi Cilt Bilgisi [dc.identifier.volume] | 103 |
| Tek Biçim Adres [dc.identifier.uri] | https://dx.doi.org/10.1016/j.hydromet.2010.03.015 |
| Tek Biçim Adres [dc.identifier.uri] | https://hdl.handle.net/20.500.12628/3717 |